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The lengthy list includes Richard Burton and Elizabeth Taylor, Alec Baldwin and Kim Basinger, Goldie Hawn and Kurt Russell, Ben Affleck and Jennifer Lopez, Affleck and Jennifer Garner, Angelina Jolie and Brad Pitt, and Tom Cruise and Nicole Kidman. "Madame Secretary" star Téa Leoni has been dating her on-screen husband, Tim Daly, for a couple of years now.